Configurational landscape of chiral iron(ii) bis(phosphane) complexes
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چکیده
منابع مشابه
Configurational Entropy in Chiral Solutions - Negative Entropy of Solvent Envelopes
A homogeneous solution of a chiral substance is acquired with an overall asymmetry which is expressed by a specific rotation of a linearly polarized light. Such a solution, despite being at a complete equilibrium, stores configurational entropy in a form of negative entropy which can be nullified by mixing with a solution of the opposite enantiomer. This abundant, yet quite a specific case of i...
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ژورنال
عنوان ژورنال: Dalton Transactions
سال: 2020
ISSN: 1477-9226,1477-9234
DOI: 10.1039/c9dt04821a